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Cross-Coupling Polymerization at Iodophenyl Thin Films Prepared by Spontaneous Grafting of a Diazonium Salt

17 February 2020, Version 2
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Development of a method for the surface-initiated Kumada cross-coupling polymerization based on 4-iodophenyldiazonium salt thin films. Studies of the kinetics of chain termination and polymer film growth, and use of this method to make polythiophene brushes.

Keywords

cross-coupling
KCTP
surface-initiated polymerization
diazonium
thin film
polythiophene
conjugated polymer

Supplementary materials

Title
Description
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Title
Marshall PeerJ Materials Science 2019 SI Revision 1
Description
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Now Published

Cross-coupling polymerization at iodophenyl thin films prepared by spontaneous grafting of a diazonium salt [opens in a new tab]
Nicholas Marshall, Andres Rodriguez journal article
PeerJ Materials Science , Volume 2
Online publication date: Apr 09, 2020

Version History

Feb 17, 2020 Version 2

Version Notes

Version 2 / Revision 1, after one round of peer review. Many experiments added, including and especially XPS of PT films and kinetics of catalyst transfer.

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License

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The content is available under CC BY NC 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.11388678.v2
D O I: 10.26434/chemrxiv.11388678.v2 [opens in a new tab]

Funding

RISE, USC OVPR 2019

Author’s competing interest statement

The authors declare no conflicts.

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