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Ruthenocenoporphyrinoids - π-Conjugation Transmitted Across 1,3-Substituted Ruthenocene

13 January 2025, Version 2
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Synthesis of ruthenocenoporphyrinoids, wherein the [RuCp*]+ moiety coordinates to the cyclopentadienyl π-surface of the 21-carba-23-selenaporphyrin macrocyclic platform has been developed. The NICS 2D maps and EDDB plots gave an insight into the aromaticity and effectiveness of π-conjugation across 1,3-substituted ruthenocene in obtained hybrid molecules.

Keywords

aromaticity
π complexation
carbaporphyrin
ruthenocene
selenophene

Supplementary materials

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Electronic Supporting Materials
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Experimental procedures, NMR, UV-vis, HRMS spectra, DFT calculations
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Supplementary weblinks

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NMR files
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NMR spectra for compound characterizations
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Version History

Jan 13, 2025 Version 2

Version Notes

Minor changes in the manuscript. Renumerated compounds and altered figures

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2024-5f7x4-v2
D O I: 10.26434/chemrxiv-2024-5f7x4-v2 [opens in a new tab]

Funding

Narodowe Centrum Nauki
2016/23/B/ST5/00161
Narodowe Centrum Nauki
2020/39/D/ST4/00021

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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