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A [CuII24] truncated octahedron and its [CuII8] building block

20 February 2025, Version 1
Working Paper
This content is an early or alternative research output and has not been peer-reviewed by Cambridge University Press at the time of posting.

Abstract

Reaction of CuCl2·2H2O with p-tert-butylthiacalix[4]arene (H4TC[4]A) affords a [CuII24] cage whose metallic skeleton conforms to a truncated octahedron in which the metal ions are strongly antiferromagnetically coupled. A structurally related [Cu8] cluster can be made using CuBr2 in an otherwise identical reaction.

Keywords

Coordination Chemistry
Molecular Magnetism
Copper
Truncated Tetrahedron

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Version History

Feb 20, 2025 Version 1

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The content is available under CC BY 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv-2025-l2tk4
D O I: 10.26434/chemrxiv-2025-l2tk4 [opens in a new tab]

Funding

Leverhulme Trust
RPG-2021-176

Author’s competing interest statement

The author(s) have declared they have no conflict of interest with regard to this content

Ethics

The author(s) have declared ethics committee/IRB approval is not relevant to this content

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